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聚合铁钛混凝剂对印染废水的处理

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石健, 万杨, 黄鑫, 石宝友, 耿建刚, 华平. 聚合铁钛混凝剂对印染废水的处理[J]. 环境工程学报, 2019, 13(5): 1021-1029. doi: 10.12030/j.cjee.201901137
引用本文: 石健, 万杨, 黄鑫, 石宝友, 耿建刚, 华平. 聚合铁钛混凝剂对印染废水的处理[J]. 环境工程学报, 2019, 13(5): 1021-1029. doi: 10.12030/j.cjee.201901137
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SHI Jian, WAN Yang, HUANG Xin, SHI Baoyou, GENG Jiangang, HUA Ping. Treating dyeing wastewater with a kind of polyferric titanium sulfate[J]. Chinese Journal of Environmental Engineering, 2019, 13(5): 1021-1029. doi: 10.12030/j.cjee.201901137
Citation: SHI Jian, WAN Yang, HUANG Xin, SHI Baoyou, GENG Jiangang, HUA Ping. Treating dyeing wastewater with a kind of polyferric titanium sulfate[J]. Chinese Journal of Environmental Engineering, 2019, 13(5): 1021-1029. doi: 10.12030/j.cjee.201901137
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聚合铁钛混凝剂对印染废水的处理

  • 1.

    南通大学分析测试中心，南通 226019

  • 2.

    南通大学纺织服装学院，南通 226019

  • 3.

    中国科学院生态环境研究中心，中国科学院饮用水科学与技术重点实验室，北京 100085

  • 4.

    中国科学院大学，北京 100049

  • 5.

    山东中科天泽净水材料有限公司，淄博 256406

  • 基金项目:

    国家自然科学基金资助项目21177067国家自然科学基金资助项目(21177067)

Treating dyeing wastewater with a kind of polyferric titanium sulfate

  • 1.

    Analysis & Testing Center, Nantong University, Nantong 226019, China

  • 2.

    School of Textile, Nantong University, Nantong 226019, China

  • 3.

    Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China

  • 4.

    University of Chinese Academy of Sciences, Beijing 100049, China

  • 5.

    Shandong Zhongke Tianze Water Purification Material Co.Ltd., Zibo 256406, China

  • Fund Project:

  • 摘要: 采用钛铁矿为主要原料，以硫酸溶出部分铁和钛，并调节Ti/Fe比、碱化度制备高效的新型含钛聚合硫酸铁混凝剂(T-PSF)，将其用于分散兰和活性黄2种模拟印染废水的脱色处理并研究其混凝去除机理。实验结果表明，在Ti/Fe为1∶6和碱化度为2.0时，制备出的T-PSF混凝效果最好。T-PSF对分散兰的去除率为94.3%，比FeCl3的去除率提高53.8%；对活性黄的去除率为34.0%，比FeCl3提高12.7%。T-PSF处理分散兰和活性黄的最佳投加量均为0.3 mmol·L-1，最佳水样初始pH分别为6和8。絮体粒径及结构分析结果表明，T-PSF处理分散兰过程中形成的絮体粒径较FeCl3大，处理活性黄过程中所形成的絮体粒径较FeCl3小，但絮体结构均比FeCl3更密实。结合T-PSF的表征、Zeta电位及絮体特性分析表明，在分散染料去除过程中，T-PSF产生的多羟基钛铁聚合物的电中和及吸附架桥起主要作用；对于活性染料的去除，主要机制为T-PSF水解产生的带正电的多羟基钛铁聚合物的吸附络合作用。
    Abstract: In this study, a new polyferric-titanium sulfate coagulant (T-PSF) was prepared through dissolving a part of iron and titanium from ilmenite with sulfuric acid and adjusting Ti/Fe ratio and basicity. The T-PSF was used to treat two kinds of simulated dye wastewater (disperse blue and reactive yellow), and its coagulation mechanisms were also discussed. The results showed that T-PSF had a good coagulation performance with the Ti/Fe ratio of 1∶6 and basicity of 2.0. The removal efficiencies of disperse blue and reactive yellow by T-PSF coagulation were 94.3% and 34.0%, which were 53.8% and 12.7% higher than those by FeCl3 coagulation, respectively. For disperse blue and reactive yellow removal, the optimal T-PSF dosages were 0.3 mmol·L-1 and the optimum pHs were 6 and 8, respectively. In compared with flocs during FeCl3 coagulating dyes, larger and more compact ones occurred during T-PSF coagulating disperse blue, while smaller and more compact one occurred during T-PSF coagulating reactive yellow. In combination with T-PSF characterization, Zeta potential and other properties of flocs, charge neutralization and bridging of polyhydroxy-ferrotitanium polymers through T-PSF hydrolysis were identified as playing a key role in disperse dyes removal, while the adsorption and complexation of positively charged polyhydroxy-ferrotitanium polymers through T-PSF hydrolysis were identified as playing a key role in reactive dyes removal.
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  • [1] KATHERESAN V, KANSEDO J, LAU S Y. Efficiency of various recent wastewater dye removal methods: A review[J]. Journal of Environmental Chemical Engineering, 2018, 6: 4676-4697.
    [2] 任南琪, 周显娇, 郭婉茜, 等. 染料废水处理技术研究进展[J]. 化工学报, 2013, 64(1): 84-94.
    [3] 韩志勇, 韩昆, 郝昊天, 等. 铜铁氧体法处理模拟染料废水[J]. 环境科学, 2018, 39(3): 1195-1201.
    [4] YAGUB M T, SEN T K, AFROZE S, et al. Dye and its removal from aqueous solution by adsorption: A review[J]. Advances in Colloid and Interface Science, 2014, 209: 172-184.
    [5] DUAN J, GREGORY J. Coagulation by hydrolysing metal salts[J]. Advances in Colloid and Interface Science, 2003, 100: 475-502.
    [6] LEI G, MA J, GUAN X, et al. Effect of basicity on coagulation performance of polyferric chloride applied in eutrophicated raw water[J]. Desalination, 2009, 247(1/2/3): 518-529.
    [7] OKOUR Y, SHON H K, EI S I. Characterisation of titanium tetrachloride and titanium sulfate flocculation in wastewater treatment[J]. Water Science & Technology, 2009, 59(12): 2463-2473.
    [8] CHEN W, ZHENG H, GUO J, et al. Preparation and characterization of a composite coagulant: Polyferric titanium sulfate[J]. Water, Air & Soil Pollution, 2016, 227(3): 79.
    [9] 薛文文. 聚硫酸铁钛混凝剂(PFTS)的制备及其在饮用水处理中的应用[D]. 重庆: 重庆大学, 2015.
    [10] 苏漫漫. 钛铁类净水剂的研发及在废水中的应用效果[D]. 济南: 济南大学, 2015.
    [11] 陈伟. 铁钛混凝剂的制备及在除藻和控制藻源膜污染中的应用研究[D]. 重庆: 重庆大学, 2016.
    [12] ZHAO S, GAO B, YUE Q, et al. Study of enteromorpha polysaccharides as a new-style coagulant aid in dye wastewater treatment[J]. Carbohydrate Polymers, 2014, 103(3): 179-186.
    [13] 黄鑫. 聚合钛盐混凝剂的研究[D]. 济南: 山东大学, 2017.
    [14] 陈伟, 郑怀礼, 翟俊, 等. 聚合硫酸铁钛混凝剂的制备及红外、紫外-可见光谱分析[J]. 光谱学与光谱分析, 2016, 36(4): 1038-1043.
    [15] 曾超. 铁碳微电解-混凝深度处理印染废水作用机制研究[D]. 上海: 东华大学, 2015.
    [16] LI R, GAO B, GUO K, et al. Effects of papermaking sludge-based polymer on coagulation behavior in the disperse and reactive dyes wastewater treatment[J]. Bioresource Technology, 2017, 240: 59-67.
    [17] 孙勇. 粉煤灰提取液合成聚硅铁混凝剂及铅絮体分形研究[D]. 济南: 济南大学, 2011.
    [18] GREGORY J, DUPON V. Properties of flocs produced by water treatment coagulants[J]. Water Science & Technology, 2001, 44(10): 231-236.
    [19] 赵艳侠. 钛盐混凝剂的混凝行为、作用机制、絮体特性和污泥回用研究[D]. 济南: 山东大学, 2014.
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  • 刊出日期:  2019-06-03

聚合铁钛混凝剂对印染废水的处理

  • 1. 南通大学分析测试中心，南通 226019
  • 2. 南通大学纺织服装学院，南通 226019
  • 3. 中国科学院生态环境研究中心，中国科学院饮用水科学与技术重点实验室，北京 100085
  • 4. 中国科学院大学，北京 100049
  • 5. 山东中科天泽净水材料有限公司，淄博 256406
基金项目:

国家自然科学基金资助项目21177067国家自然科学基金资助项目(21177067)

摘要: 采用钛铁矿为主要原料，以硫酸溶出部分铁和钛，并调节Ti/Fe比、碱化度制备高效的新型含钛聚合硫酸铁混凝剂(T-PSF)，将其用于分散兰和活性黄2种模拟印染废水的脱色处理并研究其混凝去除机理。实验结果表明，在Ti/Fe为1∶6和碱化度为2.0时，制备出的T-PSF混凝效果最好。T-PSF对分散兰的去除率为94.3%，比FeCl3的去除率提高53.8%；对活性黄的去除率为34.0%，比FeCl3提高12.7%。T-PSF处理分散兰和活性黄的最佳投加量均为0.3 mmol·L-1，最佳水样初始pH分别为6和8。絮体粒径及结构分析结果表明，T-PSF处理分散兰过程中形成的絮体粒径较FeCl3大，处理活性黄过程中所形成的絮体粒径较FeCl3小，但絮体结构均比FeCl3更密实。结合T-PSF的表征、Zeta电位及絮体特性分析表明，在分散染料去除过程中，T-PSF产生的多羟基钛铁聚合物的电中和及吸附架桥起主要作用；对于活性染料的去除，主要机制为T-PSF水解产生的带正电的多羟基钛铁聚合物的吸附络合作用。

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